Selective ligand removal to improve accessibility of active sites in hierarchical MOFs for heterogeneous photocatalysis

The dataset was generated during the synthesis, thermal treatment, characterization, and photocatalytic evaluation of titanium-based hierarchical metal–organic frameworks (MOFs) with selectively removed ligands and engineered defects.

The dataset includes raw and processed experimental data for: Powder X-ray diffraction (XRD) Simulated XRD patterns Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS) Thermogravimetric analysis (TGA) In situ temperature- and time-dependent XRD measurements In situ DRIFTS measurements Density Functional Theory (DFT) calculations Photocatalytic hydrogen evolution experiments Mixed-ligand MOF characterization and performance analysis The Excel workbook is organized into multiple sheets according to characterization technique and experimental condition.