Elucidating the impacts of COVID-19 lockdown on air quality and ozone chemical characteristics in India

While the ozone concentration decreased in most parts of the domain, it occasionally increased in major cities like Delhi and in regions with many power plants. We utilized the reaction rate information in WRF-Chem to study the ozone chemistry. We found carbon monoxide, formaldehyde, isoprene, acetaldehyde, and ethylene as the major VOCs that contribute to the ozone formation in India.

We used the ratio of radical termination from radical–radical interactions to radical–NOx interactions, and its corresponding formaldehyde to NO2 ratio (FNR) to find the ozone chemical regimes. We showed that the FNR transition range in a region depends on whether it is an urban, rural, or power plant region. Using the FNR information, we found that most parts of India are within the NOx-limited regime.

We also found that large emission reduction during the lockdown period shifted the chemical regimes toward NOx-limited although it did not necessarily change the chemical regime in many VOC-limited regions. The results of this study highlight the fact that reducing the exposure to both PM2.5 and ozone requires air pollution management strategies that consider both NOx and VOC emission reductions, and that take into account regional characteristics.