Modeling of Falling-Particle Solar Receivers for Hydrogen Production and Thermochemical Energy Storage

While the operation of the SPR is relatively simple, analysis is complicated by the many physical phenomena in the receiver, including radiation-dominated heat transfer, couple gas-particle flow, and inter-phase species transport via reaction. This work aims to demonstrate a set modeling tools for characterizing the operation of a solid particle receiver, as well as an analysis of the key operating parameters. A inert receiver model is developed using a semi-empirical gas-phase model and the surface-to-surface radiation model modified to account for interaction with the particle curtain.

A detailed thermo-kinetic model is developed for undoped-ceria, a popular material for research into solar fuel production. The inert-receiver model is extended to integrate this kinetic model, and further used to evaluate the potential of perovskite materials to enhance the storage capability of the receiver. A modified undoped ceria model is derived and implemented via custom user functions in the context of a computational fluid dynamics simulation of the receiver using the discrete-ordinates method for radiation transfer.

These modeling efforts provide a basis for in-depth analysis of the key operating parameters that influence the performance of the solid-particle receiver.