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Data · collection · 2016

Silica-modified magnetite Fe 3 O 4 nanoparticles grafted with sulfamic acid functional groups: an efficient heterogeneous catalyst for the synthesis of 3,4-dihydropyrimidin-2(1 H )-one and tetrahydrobenzo[b]pyran derivatives

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Silica-modified magnetite-polyoxometalates functionalized with sulfamic acid groups as hybrid nanoparticles were prepared by sulfonation of diamine-functionalized propyl group grafted on the magnetic silica-coated Fe 3 O 4 nanoparticles.

Description

This heterogeneous nanocatalyst was explored to present high catalytic performance for the synthesis of 3,4-dihydropyrimidinones and tetrahydrobenzo[b]pyrans under mild reaction conditions.

The properties of this nanocatalyst were characterized by FT- infrared, energy-dispersive X-ray spectrum, scanning electron microscope, X-ray diffraction, X-ray fluorescence and elemental analysis. Easy separation of the nanocatalyst by using an external magnet, recyclability, non-toxicity, versatility and high stability of the catalyst combined with low reaction times and excellent yields make the present protocol very useful and attractive for the synthesis of the titled products.

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Medicine & Health
Inferred from text
Organic chemistry 71%

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Provenance · 1 source records, 11 field assertions
SourceKeyLast seenRaw
DataCite10.6084/m9.figshare.c.326369812 d agoJSON v1
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concepts[field].anzsrc:group:3405enrichment · DataCitetaxonomy-embedding@1.1.0title+keywords+description (71%)
concepts[field].fos:chemical-sciencessource · DataCiteconnector:datacite@1.0.0
concepts[field].fos:physical-sciencessource · DataCiteconnector:datacite@1.0.0
concepts[field].local:field:medicine-healthmapping · DataCitevocabulary-mapper@1.0.0keywords['Medicine']
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