Dataset：SiO2-Coated ZIF-67-Derived Cobalt Catalyst for Hydrodeoxygenation of Guaiacol to Cyclohexanol

Hydrogen consumption signals were monitored using a thermal conductivity detector. Before the H2-TPD test, the sample was pretreated by the same procedure. After cooling to room temperature, the gas was switched to 10% H2/Ar for H2 adsorption until saturation.

The sample was then purged with flowing helium for 30 min to remove physisorbed H2, followed by heating to 600 °C at a rate of 5 °C/min for H2 temperature-programmed desorption. The amount of desorbed H2 was detected by TCD. K-Alpha X-ray photoelectron spectroscopy (XPS) was used to analyze the chemical states and relative contents of elements on the sample surface.

Raman spectroscopy (Raman) measurements were performed on a scientific LabRAM type spectrometer from HORIBA, Japan. Thermogravimetric analysis (TGA) was carried out by the HTG-1 thermogravimetric analyzer made by Beijing Hengjiu Scientific Instrument Factory. The analysis was conducted in an air atmosphere with a gas flow rate of 100 mL/min, a temperature range from room temperature to 800 °C, and a heating rate of 5 °C/min.