Structure · dataset · 2025
Crystal structure of (1,3-di-tert-butyl- η 5-cyclopentadienyl)trimethylhafnium(IV)
Listed in e-cienciaDatos
The molecule of the title organometallic hafnium(IV) compound, [Hf(CH3) 3(C 13H 21)] or [HfMe3( η 5-C 5H 3-1,3- tBu 2)], adopts the classical three-legged piano-stool geometry for monocyclopentadienylhafnium(IV) derivatives with the three methyl groups bonded to the Hf(IV) atom at the legs.
Description
The C atoms of the two tert-butyl group bonded to the cyclopentadienyl (Cp) ring are 0.132 (5) and 0.154 (6) Å above the Cp least-squares plane.
There are no significant intermolecular interactions present between the molecules in the crystal structure.
Links
Where it is published
- Dataverse dataset page edatos.consorciomadrono.es/dataset.xhtml?persistentId=doi%3A10.21950%2FBCYB9Y ↗
landing page · from edatos consorciomadrono es
- DOI doi.org/10.21950/bcyb9y ↗
DOI / persistent id · from edatos consorciomadrono es
Catalogue records · 1
- Dataverse API edatos.consorciomadrono.es/api/datasets/:persistentId/?persistentId=doi%3A10.21950%2FBCYB… ↗
metadata API · from edatos consorciomadrono es
Topics
- Stated by source
- Química
- From keywords
- Materials Science
- Inferred from text
- Inorganic chemistry 70%
Provenance · 1 source records, 9 field assertions
| Source | Key | Last seen | Raw |
|---|---|---|---|
| e-cienciaDatos | doi:10.21950/BCYB9Y | 13 d ago | JSON v1 |
| Field | Assertion | Extractor | Evidence |
|---|---|---|---|
| concepts[field].anzsrc:group:3402 | enrichment · edatos consorciomadrono es | taxonomy-embedding@1.1.0 | title+keywords+description (70%) |
| concepts[field].dataverse_subject:qu-mica | source · edatos consorciomadrono es | connector:edatos_consorciomadrono_es@1.0.0 | /subjects |
| concepts[field].local:field:materials-science | mapping · edatos consorciomadrono es | connector:edatos_consorciomadrono_es@1.0.0 | /subjects |
| created_date | source · edatos consorciomadrono es | connector:edatos_consorciomadrono_es@1.0.0 | |
| description | source · edatos consorciomadrono es | connector:edatos_consorciomadrono_es@1.0.0 | /description |
| publication_date | source · edatos consorciomadrono es | connector:edatos_consorciomadrono_es@1.0.0 | |
| title | source · edatos consorciomadrono es | connector:edatos_consorciomadrono_es@1.0.0 | /name |
| updated_date | source · edatos consorciomadrono es | connector:edatos_consorciomadrono_es@1.0.0 | |
| version_label | source · edatos consorciomadrono es | connector:edatos_consorciomadrono_es@1.0.0 |