ND_2_ rotational spectrum

Observations of deuterium-bearing species in several astronomical sources represent a powerful tool to improve our understanding of the interstellar chemistry. The doubly deuterated form of the astrophysically interesting amidogen radical could be a target of detection in space.

In this work, the rotational spectrum of the ND_2_ radical in its ground vibrational and electronic X^2^B_1_ state has been investigated between 588 and 1131GHz using a frequency modulation millimeter/submillimeter-wave spectrometer. The ND_2_ molecule has been produced in a free-space glass absorption cell by discharging a mixture of ND_3_ and Ar. Sixty-four new transition frequencies involving J values from 2 to 5 and K_a_ values from 0 to 4 have been measured.