Structure · dataset · 2024
Efficient energy transfer between Er and Dy achieved in perfluoride glass ceramics by tailoring crystallization characteristics
Listed in ScienceDB
Perfluoride glass ceramics (FGCs) with SrF2/CaF2 mixed crystals were prepared using a concurrent rapid-quenching-crystallization process.
Description
The FGCs contained dense, homogeneous, round crystals of sizes less than 1 μm with high transmittance (exceeding 80% at 3-8 μm) and low phonon energy (508 cm-1). The fluorescence properties of the FGCs doped with Er and Dy were investigated.
The energy transfer efficiency between Er and Dy reached 93.81% and 98.13%, corresponding to Er: 4I11/2 to Dy: 6H5/2 and Er: 4I13/2 to Dy: 6H11/2, respectively. This enhancement is attributed to the enrichment of rare-earth ions in the crystals induced by phase-separation and low phonon energy of the host material, FGC. Moreover, the average lifetime of Er: 4I11/2 in FGC reached 10.13 ms, which is the highest reported value for glass ceramics to our knowledge.
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This study enriches the research theory of FGC and provides guidance for expanding the properties of materials for mid-infrared photonics.
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Where it is published
- DOI doi.org/10.57760/sciencedb.13673 ↗
DOI / persistent id · from scidb cn
Catalogue records · 1
- OAI-PMH record scidb.cn/oai?verb=GetRecord&metadataPrefix=oai_dc&identifier=10.57760%2… ↗
metadata API · from scidb cn
Topics
- From keywords
- Earth & Environmental Science · Energy · Engineering · Humanities · Life Sciences · Materials Science · Social Science
- Inferred from text
- Inorganic chemistry 71%
Provenance · 1 source records, 12 field assertions
| Source | Key | Last seen | Raw |
|---|---|---|---|
| ScienceDB | 10.57760/sciencedb.13673 | 11 d ago | JSON v1 |
| Field | Assertion | Extractor | Evidence |
|---|---|---|---|
| concepts[field].anzsrc:group:3402 | enrichment · scidb cn | taxonomy-embedding@1.0.0 | title+keywords+description (71%) |
| concepts[field].local:field:earth-environmental | mapping · scidb cn | connector:scidb_cn@1.0.0 | |
| concepts[field].local:field:energy | mapping · scidb cn | connector:scidb_cn@1.0.0 | |
| concepts[field].local:field:engineering | mapping · scidb cn | connector:scidb_cn@1.0.0 | |
| concepts[field].local:field:humanities | mapping · scidb cn | connector:scidb_cn@1.0.0 | |
| concepts[field].local:field:life-sciences | mapping · scidb cn | connector:scidb_cn@1.0.0 | |
| concepts[field].local:field:materials-science | mapping · scidb cn | connector:scidb_cn@1.0.0 | |
| concepts[field].local:field:social-science | mapping · scidb cn | connector:scidb_cn@1.0.0 | |
| description | source · scidb cn | connector:scidb_cn@1.0.0 | /metadata/dc/description |
| license_text | source · scidb cn | connector:scidb_cn@1.0.0 | |
| publication_date | source · scidb cn | connector:scidb_cn@1.0.0 | |
| title | source · scidb cn | connector:scidb_cn@1.0.0 | /metadata/dc/title |