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Data · dataset · 2026

Data for "Anion Effects in Electrochemical Transistors with Semiconducting Single-Walled Carbon Nanotube Networks"

Listed in DaRUS

This dataset contains all data underlying the figures in the paper "Anion Effects in Electrochemical Transistors with Semiconducting Single-Walled Carbon Nanotube Networks" (including the supporting information).

Description

Abbreviations used in the headers of the txt-files: Id: drain current Ig: gate (leakage) current gm: transconductance L: channel length W: channel width Vshift: transfer curve shift C’: capacitance of the channel con.: concentration Cond: device conditioning cycle Abstract of the related paper: Electrochemical transistors (ECTs) rely on the migration of cations or anions toward and into a semiconducting layer under an applied gate bias to counterbalance accumulated electrons or holes and thus control the current flow through the channel.

Dense networks of purely semiconducting single-walled carbon nanotubes (s-SWCNTs) are excellent semiconductors for ECTs, as they exhibit very high carrier mobilities, excellent chemical and mechanical stability, and are insoluble in solvents or electrolytes. They are applied here to study the effects of anion size and electrolyte solvent on hole injection and transport in ECTs. We employ electrolyte solutions with chloride and perchlorate, as well as anions based on triflate and fluorinated sulfonyl imides with increasing size and different kosmotropic and chaotropic properties.

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Significant anion-dependent shifts of the transfer and transconductance curves are evident for aqueous but not organic electrolytes, while the hole mobilities are barely affected. Furthermore, the electrolyte concentration has a strong impact on the ECT characteristics for aqueous electrolytes with large anions. These findings point toward the crucial importance of ion solvation and ionic strength for the formation of electric double layers around hydrophobic carbon nanotubes and thus electrochemical doping of s-SWCNT networks in ECTs.

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Where it is published

Catalogue records · 1

Topics

Stated by source
Chemistry · Physics
From keywords
Chemistry · Physics
Provenance · 1 source records, 11 field assertions
SourceKeyLast seenRaw
DaRUSdoi:10.18419/DARUS-533810 d agoJSON v1
FieldAssertionExtractorEvidence
concepts[field].anzsrc:group:3403enrichment · darus uni stuttgart detaxonomy-embedding@1.1.0title+keywords+description (73%)
concepts[field].dataverse_subject:chemistrysource · darus uni stuttgart deconnector:darus_uni_stuttgart_de@1.0.0/subjects
concepts[field].dataverse_subject:physicssource · darus uni stuttgart deconnector:darus_uni_stuttgart_de@1.0.0/subjects
concepts[field].local:field:chemistrymapping · darus uni stuttgart deconnector:darus_uni_stuttgart_de@1.0.0/subjects
concepts[field].local:field:physicsmapping · darus uni stuttgart deconnector:darus_uni_stuttgart_de@1.0.0/subjects
created_datesource · darus uni stuttgart deconnector:darus_uni_stuttgart_de@1.0.0
descriptionsource · darus uni stuttgart deconnector:darus_uni_stuttgart_de@1.0.0/description
publication_datesource · darus uni stuttgart deconnector:darus_uni_stuttgart_de@1.0.0
titlesource · darus uni stuttgart deconnector:darus_uni_stuttgart_de@1.0.0/name
updated_datesource · darus uni stuttgart deconnector:darus_uni_stuttgart_de@1.0.0
version_labelsource · darus uni stuttgart deconnector:darus_uni_stuttgart_de@1.0.0