Data · dataset · 2026
Isocyanic acid in a global chemistry transport model: Tropospheric distribution, budget, and identification of regions with potential health impacts
Listed in National Center for Atmospheric Research
This study uses a global chemical transport model to estimate the distribution of isocyanic acid (HNCO).
Description
HNCO is toxic, and concentrations exceeding 1 ppbv have been suggested to have negative health effects. Based on fire studies, HNCO emissions were scaled to those of hydrogen cyanide (30%), resulting in yearly total emissions of 1.5 Tg for 2008, from both anthropogenic and biomass burning sources.
Loss processes included heterogeneous uptake (pH dependent), dry deposition (like formic acid), and reaction with the OH radical (k = 1 à 10â»Â¹âµ moleculeâ»Â¹ cm³ sâ»Â¹). Annual mean surface HNCO concentrations were highest over parts of China (maximum of 470 pptv), but episodic fire emissions gave much higher levels, exceeding 4 ppbv in tropical Africa and the Amazon, and exceeding 10 ppbv in Southeast Asia and Siberia.
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This suggests that large biomass burning events could result in deleterious health effects for populations in these regions. For the tropospheric budget, using the model-calculated pH the HNCO lifetime was 37 days, with the split between dry deposition and heterogeneous loss being 95%:5%. Fixing the heterogeneous loss rate at pH = 7 meant that this process dominated, accounting for ~70% of the total loss, giving a lifetime of 6 days, and resulting in upper tropospheric concentrations that were essentially zero.
However, changing the pH does not notably impact the high concentrations found in biomass burning regions. More observational data is needed to evaluate the model, as well as a better representation of the likely underestimated biofuel emissions, which could mean more populations exposed to elevated HNCO concentrations.
Links
Get the data
- Publisher page n2t.org/ark:/85065/d7df6rtg ↗
documentation · download · from data ucar edu
Where it is published
- data.ucar.edu /dataset/isocyanic-acid-in-a-global-chemistry-transport-model-t… ↗
National Center for Atmospheric Research dataset page
landing page · from data ucar edu
Catalogue records · 1
- CKAN API data.ucar.edu/api/3/action/package_show?id=bfdef969-119f-42ba-a990-7a2422f05… ↗
metadata API · from data ucar edu
Topics
- From keywords
- Earth & Environmental Science · Ocean & Atmospheric Science
Provenance · 1 source records, 7 field assertions
| Source | Key | Last seen | Raw |
|---|---|---|---|
| National Center for Atmospheric Research | bfdef969-119f-42ba-a990-7a2422f05075 | 13 d ago | JSON v1 |
| Field | Assertion | Extractor | Evidence |
|---|---|---|---|
| concepts[field].local:field:earth-environmental | mapping · data ucar edu | connector:data_ucar_edu@1.0.0 | |
| concepts[field].local:field:ocean-atmospheric | mapping · data ucar edu | connector:data_ucar_edu@1.0.0 | |
| created_date | source · data ucar edu | connector:data_ucar_edu@1.0.0 | |
| description | source · data ucar edu | connector:data_ucar_edu@1.0.0 | /notes |
| publication_date | source · data ucar edu | connector:data_ucar_edu@1.0.0 | |
| title | source · data ucar edu | connector:data_ucar_edu@1.0.0 | /title |
| updated_date | source · data ucar edu | connector:data_ucar_edu@1.0.0 |