Data · dataset · 1979
The distribution of sulfur in oceanic crust with respect to oxidative diagenesis (Table 1)
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A detailed geochemical-petrological examination of layer 2 basalts recovered during Leg 37 of the DSDP has revealed that the original distribution, form and abundance of igneous sulfide have been profoundly altered during low-grade oxidative diagenesis.
Description
The net result appears to have been a rather pervasive remobilization of igneous sulfide to form secondary pyrite accompanied by a bulk loss of sulfur equivalent to about 50-60% of the original igneous value, assuming initial saturation.
It is suggested that during infiltration of seawater into the massive crystalline rock, igneous sulfide has experienced pervasive oxidation, under conditions of limited oxidation potential, to form a series of unstable, soluble sulfur species, primarily in the form of SO3[2-] and S2O3[2-]. Spontaneous decomposition of these intermediate compounds through disproportionation has resulted in partial reconstitution of the sulfur as secondary pyrite and the generation of SO4[2-] ion, which, due to its kinetic stability, has been lost from the basalt system and ultimately transferred to the ocean.
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This model not only satisfies the geochemical and petrological observations but also provides a suitable explanation for the highly variable delta34S values which characterize secondary sulfides in deep ocean floor basalts.
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Where it is published
- Repository landing page doi.pangaea.de/10.1594/PANGAEA.710856 ↗
landing page · from DataCite
- DOI doi.org/10.1594/pangaea.710856 ↗
DOI / persistent id · from DataCite
Documentation and papers
- Creative Commons Attribution 3.0 Unported creativecommons.org/licenses/by/3.0/legalcode ↗
license · from DataCite
- IsSupplementTo 10.1016/0012-821x(79)90066-9 doi.org/10.1016/0012-821x(79)90066-9 ↗
publication · from DataCite
Catalogue records · 2
- DataCite API api.datacite.org/dois/10.1594/pangaea.710856 ↗
metadata API · from DataCite
- DataCite Commons commons.datacite.org/doi.org/10.1594/pangaea.710856 ↗
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Topics
- Inferred from text
- Tabular 65%
Provenance · 1 source records, 7 field assertions
| Source | Key | Last seen | Raw |
|---|---|---|---|
| DataCite | 10.1594/pangaea.710856 | 15 d ago | JSON v1 |
| Field | Assertion | Extractor | Evidence |
|---|---|---|---|
| access_level | source · DataCite | connector:datacite@1.0.0 | /data/attributes/rightsList |
| concepts[modality].local:modality:tabular | enrichment · DataCite | keyword-concept-rules@1.0.0 | title+description (65%) |
| description | source · DataCite | connector:datacite@1.0.0 | /data/attributes/descriptions |
| license | source · DataCite | connector:datacite@1.0.0 | /data/attributes/rightsList |
| publication_date | source · DataCite | connector:datacite@1.0.0 | /data/attributes/dates |
| spatial | source · DataCite | connector:datacite@1.0.0 | |
| title | source · DataCite | connector:datacite@1.0.0 | /data/attributes/titles/0/title |