Table · dataset · 2026
Supporting data for “AZULENE‑EMBEDDED NON‑ALTERNANT MOLECULAR CARBONS: SYNTHETIC STRATEGIES, STRUCTURAL EXPLORATION, AND OPEN‑SHELL PROPERTIES”
Listed in figshare
<h4 dir="ltr">This dataset includes the details of organic synthesis, experimental characterization results, and relevant test data, which refers to the thesis of "AZULENE‑EMBEDDED NON‑ALTERNANT MOLECULAR CARBONS: SYNTHETIC STRATEGIES, STRUCTURAL EXPLORATION, AND OPEN‑SHELL PROPERTIES” from Zhaohang LIN.
Description
This thesis focuses on the facile synthesis of fully linear non-alternant hydrocarbon to establish an unprecedented structural model, alongside the exploration of stable high-spin diradicals based on non-alternant embedded frameworks.
Firstly, building on the success of heptalene-azulene combining building block, Chapter 2 reports the synthesis of the non‑alternant PHs, diazuleno[2,1,8-efg:2',1',8'-kla]heptalene (DAH). Chemical characterization data, including mass spectra and NMR spectra were included for derivatives. In Chapter 3, this building block was extended to a non-alternant core for the preparation of diindeno-type diradicals.
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Chemical characterization data were demonstrated also with the spin testing results and calculations support. Chapter 4 explores the expansion of these modules into large non-alternant molecular carbons, detailed synthetic attempting in solution and on-surface were included. In Chapter 5, the development of an unprecedented pentalene-azulene hybrid building block were describes, pentaleno[2,1-a:5,4-a']diazulene (DAP), which was synthesized via a Pt-mediated rearrangement arylation in up to nine examples.
Chemical characterization data, including mass spectra and NMR spectra with the reaction mechanism elucidated by computational studies were demonstrated.</h4><p></p>
Links
Where it is published
- DOI doi.org/10.25442/hku.33195186.v1 ↗
DOI / persistent id · from figshare com
Catalogue records · 1
- OAI-PMH record api.figshare.com/v2/oai?verb=GetRecord&metadataPrefix=oai_dc&identifier=oai%3Af… ↗
metadata API · from figshare com
Topics
Provenance · 1 source records, 17 field assertions
| Source | Key | Last seen | Raw |
|---|---|---|---|
| figshare | oai:figshare.com:article/33195186 | 12 d ago | JSON v1 |
| Field | Assertion | Extractor | Evidence |
|---|---|---|---|
| access_level | source · figshare com | connector:figshare_com@1.0.0 | |
| concepts[field].anzsrc:field:340503 | mapping · figshare com | vocabulary-mapper@1.0.0 | keywords['Organic chemical synthesis'] |
| concepts[field].local:field:astronomy | mapping · figshare com | connector:figshare_com@1.0.0 | |
| concepts[field].local:field:chemistry | mapping · figshare com | connector:figshare_com@1.0.0 | |
| concepts[field].local:field:computer-science-ai | mapping · figshare com | connector:figshare_com@1.0.0 | |
| concepts[field].local:field:earth-environmental | mapping · figshare com | connector:figshare_com@1.0.0 | |
| concepts[field].local:field:economics-finance | mapping · figshare com | connector:figshare_com@1.0.0 | |
| concepts[field].local:field:engineering | mapping · figshare com | connector:figshare_com@1.0.0 | |
| concepts[field].local:field:humanities | mapping · figshare com | connector:figshare_com@1.0.0 | |
| concepts[field].local:field:life-sciences | mapping · figshare com | connector:figshare_com@1.0.0 | |
| concepts[field].local:field:medicine-health | mapping · figshare com | connector:figshare_com@1.0.0 | |
| concepts[field].local:field:ocean-atmospheric | mapping · figshare com | connector:figshare_com@1.0.0 | |
| concepts[field].local:field:social-science | mapping · figshare com | connector:figshare_com@1.0.0 | |
| description | source · figshare com | connector:figshare_com@1.0.0 | /metadata/dc/description |
| license | source · figshare com | connector:figshare_com@1.0.0 | /metadata/dc/rights |
| publication_date | source · figshare com | connector:figshare_com@1.0.0 | |
| title | source · figshare com | connector:figshare_com@1.0.0 | /metadata/dc/title |