Data · dataset · 2026
Construction of Clathrochelate-Bridged Covalent Organic Frameworks via Coordinate and Covalent Bonding
Listed in ScienceDB
we establish a synergistic co-assembly strategy integrating metal-ligand coordination with dynamic covalent B−O−N linkages for one-pot synthesis of a three-dimensional clathrochelate-bridged COF (Fe-CC-COF).
Description
Using an oxime ligand, FeCl2, and a tetrahedral boronate under kinetically synchronized conditions, we achieved high crystallinity and porosity. X-ray absorption fine structure (XAFS) spectroscopy confirmed well-defined FeN6 coordination.
The framework exhibits reversible transitions between chelate-linked and metal-cage configurations and allows post-synthetic incorporation of diverse metal ions (M = Co2+, Ni2+, Cu2+, Zn2+), expanding the M-CC-COF family.
Links
Where it is published
- DOI doi.org/10.57760/sciencedb.30974 ↗
DOI / persistent id · from scidb cn
Catalogue records · 1
- OAI-PMH record scidb.cn/oai?verb=GetRecord&metadataPrefix=oai_dc&identifier=10.57760%2… ↗
metadata API · from scidb cn
Topics
- From keywords
- Earth & Environmental Science · Engineering · Humanities · Life Sciences · Social Science
Provenance · 1 source records, 10 field assertions
| Source | Key | Last seen | Raw |
|---|---|---|---|
| ScienceDB | 10.57760/sciencedb.30974 | 12 d ago | JSON v1 |
| Field | Assertion | Extractor | Evidence |
|---|---|---|---|
| access_level | source · scidb cn | connector:scidb_cn@1.0.0 | |
| concepts[field].local:field:earth-environmental | mapping · scidb cn | connector:scidb_cn@1.0.0 | |
| concepts[field].local:field:engineering | mapping · scidb cn | connector:scidb_cn@1.0.0 | |
| concepts[field].local:field:humanities | mapping · scidb cn | connector:scidb_cn@1.0.0 | |
| concepts[field].local:field:life-sciences | mapping · scidb cn | connector:scidb_cn@1.0.0 | |
| concepts[field].local:field:social-science | mapping · scidb cn | connector:scidb_cn@1.0.0 | |
| description | source · scidb cn | connector:scidb_cn@1.0.0 | /metadata/dc/description |
| license_text | source · scidb cn | connector:scidb_cn@1.0.0 | |
| publication_date | source · scidb cn | connector:scidb_cn@1.0.0 | |
| title | source · scidb cn | connector:scidb_cn@1.0.0 | /metadata/dc/title |