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Data · dataset · 2026

Preparation and Tribological Performances of Polyurea-type Ionic Liquid Water-based Lubrication Additives

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Compared with oil-based lubricants, water-based lubricant systems possess excellent cooling and flame-retardant properties, offering great application potential in many fields.

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However, the highly polar water molecules usually weaken the interactions between water-based lubricant additives and interfaces, thereby hindering the formation of the interfacial adsorption layer and ultimately resulting in poor extreme pressure load-carrying capacity of water-based lubricants.

In this study, a polyurea-type ionic liquid was prepared as a water-based lubricant additive. The hydrogen bonding interactions between urea groups enabled the polymer to form a more stable adsorption layer at the interface. The existence of a large number of hydrogen bonds and tribo-chemical films in the polyurea-type ionic liquid was confirmed by multiple characterization technologies (temperature-dependent FTIR, two-dimensional IR, XPS and QCM-D).

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By comparing the effects of small molecule ionic liquids and polyurea units with different rigidity on the tribological performances of water-based lubricants, it was proved that the synergistic effect of multiple non-covalent interactions (hydrogen bonding, electrostatic interactions and hydrophobic effects) in polyurea ionic liquids can significantly improve the anti-friction, anti-wear performance, and extreme pressure load-carrying capacity of the water-based lubrication system.

The final polyurea-based ionic liquid achieved a coefficient of friction as low as 0.12 and an extreme pressure capacity up to 1000 N at a concentration of 2%, while the corrosion to metals was significantly reduced.

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