Data · dataset · 2026
Towards induction of charge-transfer complexation in ionic liquid systems
Listed in ZivaHub and Deakin Research Online and DMU Figshare — shown once because both records carry DOI 10.17034/32635176.v1
Charge-transfer complexes are formed by the interactions of electron donor and electron acceptor functions.
Description
In this work, a series of imidazolium-based ionic liquids functionalised with electron-rich aromatic groups have been synthesised and their potential to form binary ionic liquid eutectic mixtures exhibiting charge-transfer complex characteristics when combined with ‘electron-withdrawing’ cyanopyridinium cations has been investigated.
It was determined that CT complex formation is unfavourable due to competing cation-cation coulombic repulsions between pairs of cations and an alternative approach to generate solely ionic liquid CT complexes by including both electron donors and acceptor in a single aromatic-functionalized cyanopyridinium cation was also investigated.
Links
Where it is published
- DOI doi.org/10.17034/32635176.v1 ↗
DOI / persistent id · from zivahub uct ac za
Catalogue records · 1
- OAI-PMH record api.figshare.com/v2/oai?verb=GetRecord&metadataPrefix=oai_dc&identifier=oai%3Af… ↗
metadata API · from zivahub uct ac za
Topics
- From keywords
- Earth & Environmental Science · Earth & Environmental Science · Earth & Environmental Science
- Inferred from text
- Computed tomography 50%
Provenance · 3 source records, 8 field assertions
| Source | Key | Last seen | Raw |
|---|---|---|---|
| ZivaHub | oai:figshare.com:article/32635176 | 13 d ago | JSON v1 |
| Deakin Research Online | oai:figshare.com:article/32635176 | 13 d ago | JSON v1 |
| DMU Figshare | oai:figshare.com:article/32635176 | 13 d ago | JSON v1 |
| Field | Assertion | Extractor | Evidence |
|---|---|---|---|
| concepts[field].local:field:earth-environmental | mapping · zivahub uct ac za | connector:zivahub_uct_ac_za@1.0.0 | |
| concepts[field].local:field:earth-environmental | mapping · figshare dmu ac uk | connector:figshare_dmu_ac_uk@1.0.0 | |
| concepts[field].local:field:earth-environmental | mapping · dro deakin edu au | connector:dro_deakin_edu_au@1.0.0 | |
| concepts[modality].local:modality:ct | enrichment · zivahub uct ac za | keyword-concept-rules@1.0.0 | title+description (50%) |
| description | source · zivahub uct ac za | connector:zivahub_uct_ac_za@1.0.0 | /metadata/dc/description |
| license_text | source · zivahub uct ac za | connector:zivahub_uct_ac_za@1.0.0 | |
| publication_date | source · zivahub uct ac za | connector:zivahub_uct_ac_za@1.0.0 | |
| title | source · zivahub uct ac za | connector:zivahub_uct_ac_za@1.0.0 | /metadata/dc/title |