Archive · collection · 2000
Chemical composition of phillipsites from Core AKO26-35
Listed in PANGAEA
Behavior of rare earth elements (REE) was examined in oceanic phillipsites collected from four horizons of eupelagic clay in the Southwest Basin of the Pacific Ocean.
Description
REE concentrations were determined in >50 ?m size fraction phillipsite samples by the ICP-MS method. Composition of separate phillipsite aggregates was studied by electron microprobe and secondary ion mass-spectrometry.
Rare earth elements in phillipsite samples are related to admixture of ferrocalcium hydroxophosphates. Analysis of separate phillipsite aggregates reveals low (<0.1-18.1 ppm) REE(III) concentrations. Ce concentration varies between 2.7 and 140 ppm.
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The correlation analysis shows that REE(III) present in admixture of iron oxyhydroxides in separate phillipsite aggregates. Based on the REE(III) concentration in iron oxyhydroxides we can identify two generations of phillipsite aggregates. Massive rounded aggregates (phillipsite I) are depleted in REE, while pseudorhombic (phillipsite II) aggregates are enriched in REE and marked by a positive Ce anomaly.
Oceanic phillipsites do not accumulate REE or inherit the REE signature of volcaniclastic material and oceanic deep water. Hence, REE distribution in phillipsites does not depend on sedimentation rate and composition of host sediments.
Links
Where it is published
- DOI doi.org/10.1594/pangaea.783721 ↗
DOI / persistent id · from PANGAEA
Catalogue records · 1
- OAI-PMH record ws.pangaea.de/oai/provider?verb=GetRecord&metadataPrefix=oai_dc&identifier=o… ↗
metadata API · from PANGAEA
Topics
- From keywords
- Earth & Environmental Science
Provenance · 1 source records, 7 field assertions
| Source | Key | Last seen | Raw |
|---|---|---|---|
| PANGAEA | oai:pangaea.de:doi:10.1594/PANGAEA.783721 | 15 d ago | JSON v1 |
| Field | Assertion | Extractor | Evidence |
|---|---|---|---|
| access_level | source · PANGAEA | connector:pangaea@1.0.0 | |
| concepts[field].local:field:earth-environmental | mapping · PANGAEA | connector:pangaea@1.0.0 | |
| description | source · PANGAEA | connector:pangaea@1.0.0 | /metadata/dc/description |
| license | source · PANGAEA | connector:pangaea@1.0.0 | /metadata/dc/rights |
| publication_date | source · PANGAEA | connector:pangaea@1.0.0 | |
| spatial | source · PANGAEA | connector:pangaea@1.0.0 | |
| title | source · PANGAEA | connector:pangaea@1.0.0 | /metadata/dc/title |