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Data · dataset · 2025

Badanie hydratacji alitu w obecności zeolitów o niskiej i wysokiej zawartości krzemionki

Listed in ROCK Repository of Open Collections and Knowledge

<jats:title>Abstract</jats:title><jats:p>Synthetic zeolites that are obtained from the hydrothermal reaction of NaOH with fly ash have a well-defined pore structure and pozzolanic properties.

Description

This work examines the effect of the low-silica (Na-A) and high-silica (ZSM-5) zeolite structure on the kinetics of alite hydration and mineralogical characteristics of the reaction products. The addition of the Na-A and ZSM-5 zeolites reduced the rate of heat release during the hydration reaction, which is typical for commonly used pozzolanic additives.

The ZSM-5 zeolite had a much higher Si/Al ratio relative to the Na-A zeolite, which translated into a higher pozzolanic activity and resulted in greater stability of the hydration reaction kinetics. The addition of zeolites caused the heat of hydration to decrease compared to the reference pastes (the alite reference paste—206 J/g): Na-A 15%—148.9 J/g; ZSM-5 15%—149.9 J/g. The concentration of calcium ions in the alite solution and the content of active silica were identified as the most important parameters affecting the kinetic, morphological, and structural characteristics of the C–S–H phase.

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The addition of zeolites increased the amount of C–S–H gel phases formed. At the same time, the proportion of portlandite in the hydration products of the alite–zeolite systems decreased. Pozzolans reduced the ratio of CaO/SiO<jats:sub>2</jats:sub> in the C–S–H phase, which for pastes with the addition of the Na-A ranged from 1.61 to 1.37, and for the ZSM-5 from 1.91 to 0.47.

This ratio decreased with the dosage and the age of alite paste. In summary, this research has shown that synthetic zeolites are a viable pozzolanic additives.</jats:p>

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ROCK Repository of Open Collections and Knowledgeoai:rock.pollub.pl:20.500.14629/185335 d agoJSON v1
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access_levelsource · rock pollub plconnector:rock_pollub_pl@1.0.0
concepts[field].local:field:earth-environmentalmapping · rock pollub plconnector:rock_pollub_pl@1.0.0
descriptionsource · rock pollub plconnector:rock_pollub_pl@1.0.0/metadata/dc/description
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titlesource · rock pollub plconnector:rock_pollub_pl@1.0.0/metadata/dc/title