Data · dataset · 2026
Electrochemical One-Pot Diverse C(sp<sup>3</sup>)–X Bond (Including C–H, C–C, C–N, and C–O) Transformations and C(sp<sup>2</sup>)–H Acyloxylation of Alkylarenes
Listed in ZivaHub and Deakin Research Online and DMU Figshare — shown once because both records carry DOI 10.1021/acs.joc.6c01447.s001
In this study, an electrochemical one-pot cleavage of diverse C(sp<sup>3</sup>)–X bonds and acyloxylation of C(sp<sup>2</sup>)–H were reported.
Description
Based on the experimental results, we discovered for the first time that NH<sub>3</sub> can strongly promote electrolyte dissolution and significantly increase the conductivity of a solution. Unlike previous C(sp<sup>2</sup>)–H acetoxylation reactions in which AcO<sup>–</sup> functions as a nucleophile, this reaction undergoes an acetoxy radical mechanism and prevents decarboxylation of the acetoxy radical.
This reaction is advantageous because it is transition-metal-free, external-oxidant-free, atom- and step-economical, and applicable to diverse substrates; additionally, it uses mild reaction conditions and green and nontoxic solvents.
Links
Where it is published
- DOI doi.org/10.1021/acs.joc.6c01447.s001 ↗
DOI / persistent id · from zivahub uct ac za
Catalogue records · 1
- OAI-PMH record api.figshare.com/v2/oai?verb=GetRecord&metadataPrefix=oai_dc&identifier=oai%3Af… ↗
metadata API · from zivahub uct ac za
Topics
- From keywords
- Chemistry · Chemistry · Chemistry · Earth & Environmental Science · Earth & Environmental Science · Earth & Environmental Science · Ecology · Ecology · Ecology · Life Sciences · Life Sciences · Life Sciences
Provenance · 3 source records, 17 field assertions
| Source | Key | Last seen | Raw |
|---|---|---|---|
| ZivaHub | oai:figshare.com:article/34033323 | 11 d ago | JSON v1 |
| Deakin Research Online | oai:figshare.com:article/34033323 | 11 d ago | JSON v1 |
| DMU Figshare | oai:figshare.com:article/34033323 | 10 d ago | JSON v1 |
| Field | Assertion | Extractor | Evidence |
|---|---|---|---|
| access_level | source · zivahub uct ac za | connector:zivahub_uct_ac_za@1.0.0 | |
| concepts[field].anzsrc:group:3103 | mapping · figshare dmu ac uk | vocabulary-mapper@1.0.0 | keywords['Ecology'] |
| concepts[field].anzsrc:group:3103 | mapping · zivahub uct ac za | vocabulary-mapper@1.0.0 | keywords['Ecology'] |
| concepts[field].anzsrc:group:3103 | mapping · dro deakin edu au | vocabulary-mapper@1.0.0 | keywords['Ecology'] |
| concepts[field].local:field:chemistry | mapping · zivahub uct ac za | connector:zivahub_uct_ac_za@1.0.0 | |
| concepts[field].local:field:chemistry | mapping · figshare dmu ac uk | connector:figshare_dmu_ac_uk@1.0.0 | |
| concepts[field].local:field:chemistry | mapping · dro deakin edu au | connector:dro_deakin_edu_au@1.0.0 | |
| concepts[field].local:field:earth-environmental | mapping · figshare dmu ac uk | connector:figshare_dmu_ac_uk@1.0.0 | |
| concepts[field].local:field:earth-environmental | mapping · zivahub uct ac za | connector:zivahub_uct_ac_za@1.0.0 | |
| concepts[field].local:field:earth-environmental | mapping · dro deakin edu au | connector:dro_deakin_edu_au@1.0.0 | |
| concepts[field].local:field:life-sciences | mapping · dro deakin edu au | connector:dro_deakin_edu_au@1.0.0 | |
| concepts[field].local:field:life-sciences | mapping · zivahub uct ac za | connector:zivahub_uct_ac_za@1.0.0 | |
| concepts[field].local:field:life-sciences | mapping · figshare dmu ac uk | connector:figshare_dmu_ac_uk@1.0.0 | |
| description | source · zivahub uct ac za | connector:zivahub_uct_ac_za@1.0.0 | /metadata/dc/description |
| license | source · zivahub uct ac za | connector:zivahub_uct_ac_za@1.0.0 | /metadata/dc/rights |
| publication_date | source · zivahub uct ac za | connector:zivahub_uct_ac_za@1.0.0 | |
| title | source · zivahub uct ac za | connector:zivahub_uct_ac_za@1.0.0 | /metadata/dc/title |