Table · dataset · 2015
Millimeter wave spectrum of vinyl acetate
Listed in IVOA Registry (Virtual Observatory)
Description
The recent discovery of methyl acetate in Orion KL makes vinyl acetate, CH3-(C=O)-O-CH=CH2, a potential molecule in the interstellar medium.We obtained very accurate spectroscopic constants in a comprehensive laboratory analysis of its rotational spectra which can be used to predict those transition frequencies towards interstellar sources. We present the experimental study and theoretical analysis of the ground torsional state of vinyl acetate in a large spectral range for astrophysical use.
The room-temperature rotational spectrum of vinyl acetate has been measured from 125 to 305GHz to provide direct frequencies to the astronomical community. Additional measurements have also been made using a broadband CP-FTMWspectrometer in the region of 6 - 18 GHz. Transition lines, corresponding to the most stable conformer, have been observed and assigned.
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All the rotational transitions revealed the A-E splitting due to the methyl internal rotation and had to be treated with a specific internal rotation code (BELGI-Cs). We analyzed 2508 transitions up to J"=75 for vt=0 for the most stable conformer of vinyl acetate. The new lines were globally fitted with previously published data and 24 parameters of the Hamiltonian were accurately determined.
The spectral features of vinyl acetate were then searched for in Orion KL. Using the whole line survey of Orion KL (80-280GHz) obtained with the IRAM 30m radio telescope we can provide only an upper limit to the column density of vinyl acetate. However, using the ALMA Science Verification data we obtain a tentative detection of this species that will require further search at other frequencies to confirm its presence in this high mass star forming region.
Links
Where it is published
- Reference page cdsarc.cds.unistra.fr/viz-bin/cat/J/A+A/577/A91 ↗
landing page · from IVOA Registry
Documentation and papers
- ADS 2015A&A...577A..91K ui.adsabs.harvard.edu/abs/2015A%26A...577A..91K ↗
publication · from IVOA Registry
Catalogue records · 2
- VOResource record dc.g-vo.org/oai.xml?verb=GetRecord&metadataPrefix=ivo_vor&identifier=ivo%3… ↗
metadata API · from IVOA Registry
- Registry record (GAVO) dc.g-vo.org/I/cds.vizier/j/a%2Ba/577/a91 ↗
catalogue entry · from IVOA Registry
Topics
- From keywords
- Astronomy & Astrophysics
Provenance · 1 source records, 7 field assertions
| Source | Key | Last seen | Raw |
|---|---|---|---|
| IVOA Registry (Virtual Observatory) | ivo://cds.vizier/j/a+a/577/a91 | 15 d ago | JSON v1 |
| Field | Assertion | Extractor | Evidence |
|---|---|---|---|
| access_level | source · IVOA Registry | connector:ivoa_registry@1.0.0 | |
| concepts[field].local:field:astronomy | mapping · IVOA Registry | connector:ivoa_registry@1.0.0 | |
| description | source · IVOA Registry | connector:ivoa_registry@1.0.0 | rr.resource.res_description |
| license_text | source · IVOA Registry | connector:ivoa_registry@1.0.0 | |
| publication_date | source · IVOA Registry | connector:ivoa_registry@1.0.0 | |
| title | source · IVOA Registry | connector:ivoa_registry@1.0.0 | rr.resource.res_title |
| updated_date | source · IVOA Registry | connector:ivoa_registry@1.0.0 |