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Data · dataset · 2022

Analytical data belonging to the publication "Harnessing the polymer-particle duality of ultra-soft nanogels to stabilise smart emulsions"

Listed in RADAR and RADAR4Memory — shown once because both records carry DOI 10.22000/680

Micro- and nanogels are widely used to stabilise emulsions and simultaneously implement their responsiveness to the external stimuli.

Description

One of the factors that improves the emulsion stability is the nanogel softness. Here, we study how the softest nanogels that can be synthesised with precipitation polymerisation of N-isopropylacrylamide (NIPAM), the ultra-low crosslinked (ULC) nanogels, stabilise oil-in-water emulsions.

We show that ULC nanogels can efficiently stabilise emulsions already at low mass concentrations. These emulsions are resistant to droplet flocculation, stable against coalescence, and can be easily broken upon an increase in temperature. The resistance to flocculation of the ULC-stabilised emulsion droplets is similar to the one of emulsions stabilised by linear pNIPAM.

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In contrast, the stability against coalescence and the temperature-responsiveness closely resemble the one of emulsions stabilised by regularly crosslinked pNIPAM nanogels. The reason for this combination of properties is that ULC nanogels can be thought of as colloids in between flexible macromolecules and particles. As a polymer, ULC nanogels can efficiently stretch at the interface and cover it uniformly.

As a regularly crosslinked nanogel particle, ULC nanogels protect emulsion droplets against coalescence by providing a steric barrier and rapidly respond to changes in external stimuli thus breaking the emulsion. This polymer-particle duality of ULC nanogels can be exploited to improve the properties of emulsions for various applications, for example in heterogeneous catalysis or in food science.

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Where it is published

Catalogue records · 1

Topics

Inferred from text
Condensed matter physics 72%
Provenance · 2 source records, 10 field assertions
SourceKeyLast seenRaw
RADAR10.22000/68013 d agoJSON v1
RADAR4Memory10.22000/68013 d agoJSON v1
FieldAssertionExtractorEvidence
access_levelsource · radar service eu deconnector:radar_service_eu_de@1.0.0
concepts[field].anzsrc:group:5104enrichment · radar service eu detaxonomy-embedding@1.1.0title+keywords+description (72%)
concepts[field].local:field:earth-environmentalmapping · radar service eu deconnector:radar_service_eu_de@1.0.0
concepts[field].local:field:earth-environmentalmapping · radar4memory radar service euconnector:radar4memory_radar_service_eu@1.0.0
concepts[field].local:field:physicsmapping · radar service eu deconnector:radar_service_eu_de@1.0.0
concepts[field].local:field:physicsmapping · radar4memory radar service euconnector:radar4memory_radar_service_eu@1.0.0
descriptionsource · radar service eu deconnector:radar_service_eu_de@1.0.0/metadata/dc/description
licensesource · radar service eu deconnector:radar_service_eu_de@1.0.0/metadata/dc/rights
publication_datesource · radar service eu deconnector:radar_service_eu_de@1.0.0
titlesource · radar service eu deconnector:radar_service_eu_de@1.0.0/metadata/dc/title