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Archive · collection · 2016

Calcite saturation and yield and Mg/Ca, Mn/Ca, Al/Ca, Fe/Ca for four species of planktic foraminifera cleaned using Mg-cleaning and Cd-cleaning methods

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Four species of planktic foraminifera from core-tops spanning a depth transect on the Ontong Java Plateau were prepared for Mg/Ca analysis both with (Cd-cleaning) and without (Mg-cleaning) a reductive cleaning step.

Description

Reductive cleaning caused etching of foraminiferal calcite, focused on Mg-rich inner calcite, even on tests which had already been partially dissolved at the seafloor. Despite corrosion, there was no difference in Mg/Ca of Pulleniatina obliquiloculata between cleaning methods.

Reductive cleaning decreased Mg/Ca by an average (all depths) of ~ 4% for Globigerinoides ruber white and ~ 10% for Neogloboquadrina dutertrei. Mg/Ca of Globigerinoides sacculifer (above the calcite saturation horizon only) was 5% lower after reductive cleaning. The decrease in Mg/Ca due to reductive cleaning appeared insensitive to preservation state for G. ruber, N. dutertrei and P. obliquiloculata.

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Mg/Ca of Cd-cleaned G. sacculifer appeared less sensitive to dissolution than that of Mg-cleaned. Mg-cleaning is adequate, but SEM and contaminants (Al/Ca, Fe/Ca and Mn/Ca) show that Cd-cleaning is more effective for porous species. A second aspect of the study addressed sample loss during cleaning.

Lower yield after Cd-cleaning for G. ruber, G. sacculifer and N. dutertrei confirmed this to be the more aggressive method. Strongest correlations between yield and Delta[CO3^2-] in core-top samples were for Cd-cleaned G. ruber (r = 0.88, p = 0.020) and Cd-cleaned P. obliquiloculata (r = 0.68, p = 0.030). In a down-core record (WIND28K) correlation, r, between yield values > 30% and dissolution index, XDX, was -0.61 (p = 0.002).

Where cleaning yield < 30% most Mg-cleaned Mg/Ca values were biased by dissolution.

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Provenance · 1 source records, 7 field assertions
SourceKeyLast seenRaw
PANGAEAoai:pangaea.de:doi:10.1594/PANGAEA.85797415 d agoJSON v1
FieldAssertionExtractorEvidence
access_levelsource · PANGAEAconnector:pangaea@1.0.0
concepts[field].local:field:earth-environmentalmapping · PANGAEAconnector:pangaea@1.0.0
descriptionsource · PANGAEAconnector:pangaea@1.0.0/metadata/dc/description
licensesource · PANGAEAconnector:pangaea@1.0.0/metadata/dc/rights
publication_datesource · PANGAEAconnector:pangaea@1.0.0
spatialsource · PANGAEAconnector:pangaea@1.0.0
titlesource · PANGAEAconnector:pangaea@1.0.0/metadata/dc/title