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Summertime influence of Asian pollution in the free troposphere over North America

Listed in National Center for Atmospheric Research

We analyze aircraft observations obtained during INTEX-A (1 July to 14 August 2004) to examine the summertime influence of Asian pollution in the free troposphere over North America.

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By applying correlation analysis and principal component analysis (PCA) to the observations between 6 and 12 km, we find dominant influences from recent convection and lightning (13% of observations), Asia (7%), the lower stratosphere (7%), and boreal forest fires (2%), with the remaining 71% assigned to background.

Asian air masses are marked by high levels of CO, O₃, HCN, PAN, C₂H₂, C₆H₆, methanol, and SO₄ 2- . The partitioning of NO y species in the Asian plumes is dominated by PAN (∼600 pptv), with varying NO x /HNO₃ ratios in individual plumes, consistent with individual transit times of 3–9 days. Export of Asian pollution occurred in warm conveyor belts of midlatitude cyclones, deep convection, and in typhoons.

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Compared to Asian outflow measurements during spring, INTEX-A observations display lower levels of anthropogenic pollutants (CO, C₃H₈, C₂H6, C₆H₆) due to shorter summer lifetimes; higher levels of biogenic tracers (methanol and acetone) because of a more active biosphere; and higher levels of PAN, NO x , HNO₃, and O₃ reflecting active photochemistry, possibly enhanced by efficient NO y export and lightning. The high ΔO₃/ΔCO ratio (0.76 mol/mol) in Asian plumes during INTEX-A is due to strong photochemical production and, in some cases, mixing with stratospheric air along isentropic surfaces.

The GEOS-Chem global model captures the timing and location of the Asian plumes. However, it significantly underestimates the magnitude of observed enhancements in CO, O₃, PAN and NO x .

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concepts[field].local:field:earth-environmentalmapping · data ucar educonnector:data_ucar_edu@1.0.0
concepts[field].local:field:ocean-atmosphericmapping · data ucar educonnector:data_ucar_edu@1.0.0
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