Data · collection · 2016
Kinetic analysis of the mechanochemical syntheses of dialkyl 2,2′-bipyridyl-4,4′-dicarboxylate complexes of palladium
Listed in DataCite
Kinetic models for the ‘molecular’ mechanochemical syntheses of α- and β-dialkyl 2,2′-bipyridyl-4,4′-dicarboxylate complexes of palladium (PdL n I 2 , where n specifies the number of carbons in the alkyl chain of the ligand and α and β refer to the substitution of the alkyl chain) are explored.
Description
The Johnson–Mehl–Avrami–Yerofeev–Kolmogrov (JMAYK) model was determined to best fit the data obtained via 1 H NMR spectroscopic analysis of the reaction mixtures over time.
A rate enhancement, and corresponding increase in the Avrami exponent, was observed when the complex formed was liquid crystalline at milling temperatures.
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Where it is published
- Repository landing page figshare.com/collections/Kinetic_analysis_of_the_mechanochemical_syntheses_… ↗
landing page · from DataCite
- DOI doi.org/10.6084/m9.figshare.c.2854474.v1 ↗
DOI / persistent id · from DataCite
Documentation and papers
- CC-BY creativecommons.org/licenses/by/3.0/us ↗
license · from DataCite
- IsSupplementTo 10.1080/02678292.2016.1157633 doi.org/10.1080/02678292.2016.1157633 ↗
publication · from DataCite
Catalogue records · 2
- DataCite API api.datacite.org/dois/10.6084/m9.figshare.c.2854474.v1 ↗
metadata API · from DataCite
- DataCite Commons commons.datacite.org/doi.org/10.6084/m9.figshare.c.2854474.v1 ↗
catalogue entry · from DataCite
Topics
- Stated by source
- Biological sciences · Chemical sciences · Physical sciences
- From keywords
- Biochemistry and cell biology · Microbiology
Related
Provenance · 1 source records, 10 field assertions
| Source | Key | Last seen | Raw |
|---|---|---|---|
| DataCite | 10.6084/m9.figshare.c.2854474.v1 | 12 d ago | JSON v1 |
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|---|---|---|---|
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| concepts[field].fos:biological-sciences | source · DataCite | connector:datacite@1.0.0 | |
| concepts[field].fos:chemical-sciences | source · DataCite | connector:datacite@1.0.0 | |
| concepts[field].fos:physical-sciences | source · DataCite | connector:datacite@1.0.0 | |
| created_date | source · DataCite | connector:datacite@1.0.0 | |
| description | source · DataCite | connector:datacite@1.0.0 | /data/attributes/descriptions |
| license | source · DataCite | connector:datacite@1.0.0 | /data/attributes/rightsList |
| publication_date | source · DataCite | connector:datacite@1.0.0 | /data/attributes/dates |
| title | source · DataCite | connector:datacite@1.0.0 | /data/attributes/titles/0/title |
| updated_date | source · DataCite | connector:datacite@1.0.0 |