Data · collection · 2015
Morphology and Wettability Tunable Organogel System Based on An 1,3,4-Oxadiazole Derivative
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A new low molecular mass organic gelator (LMOG) bearing 1,3,4-oxadiazole and azobenzene groups, namely N-(3,4,5-octanoxyphenyl)-N’-4-[(4-hydroxyphenyl)azophenyl] 1,3,4-oxadiazole (AOB-t8), was designed and synthesized.
Description
The organogelator has shown great ability to gel a variety of organic solvents to form stable organogels with the critical gelation concentration as low as 5.0 × 10 −4 M and, therefore, can be considered a supergelator.
It has been demonstrated that the aggregation morphology and surface wettability produced by organogels strongly depend on the nature of gelling solvents. A structure of uptwisting fibers on the substrate and superhydrophobicity were observed in the xerogel formed from 1,2-dichloroethane. The wettability of the xerogel could also be tuned by applying a sol-gel process with different solvents.
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Cooperation of hydrogen bonding, π-π interaction, and Van der Waals force are suggested to be the main contribution for this self-assembled structure. The unique and tunable surface properties such as superhydrophobicity distinguish the obtained organogels as a novel class of functional materials.
Links
Where it is published
- Repository landing page tandf.figshare.com/collections/Morphology_and_Wettability_Tunable_Organogel_Syste… ↗
landing page · from DataCite
- DOI doi.org/10.6084/m9.figshare.c.1986224 ↗
DOI / persistent id · from DataCite
Documentation and papers
Catalogue records · 2
- DataCite API api.datacite.org/dois/10.6084/m9.figshare.c.1986224 ↗
metadata API · from DataCite
- DataCite Commons commons.datacite.org/doi.org/10.6084/m9.figshare.c.1986224 ↗
catalogue entry · from DataCite
Topics
- Stated by source
- Biological sciences · Chemical sciences · Health sciences
- From keywords
- Chemistry · Ecology · Infectious diseases · Inorganic chemistry · Life Sciences · Physics
Related
Provenance · 1 source records, 13 field assertions
| Source | Key | Last seen | Raw |
|---|---|---|---|
| DataCite | 10.6084/m9.figshare.c.1986224 | 15 d ago | JSON v1 |
| Field | Assertion | Extractor | Evidence |
|---|---|---|---|
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| concepts[field].fos:biological-sciences | source · DataCite | connector:datacite@1.0.0 | |
| concepts[field].fos:chemical-sciences | source · DataCite | connector:datacite@1.0.0 | |
| concepts[field].fos:health-sciences | source · DataCite | connector:datacite@1.0.0 | |
| concepts[field].local:field:chemistry | mapping · DataCite | vocabulary-mapper@1.0.0 | keywords['Chemistry'] |
| concepts[field].local:field:life-sciences | mapping · DataCite | vocabulary-mapper@1.0.0 | keywords['Biological Sciences'] |
| concepts[field].local:field:physics | mapping · DataCite | vocabulary-mapper@1.0.0 | keywords['Physics'] |
| created_date | source · DataCite | connector:datacite@1.0.0 | |
| description | source · DataCite | connector:datacite@1.0.0 | /data/attributes/descriptions |
| license | source · DataCite | connector:datacite@1.0.0 | /data/attributes/rightsList |
| publication_date | source · DataCite | connector:datacite@1.0.0 | /data/attributes/dates |
| title | source · DataCite | connector:datacite@1.0.0 | /data/attributes/titles/0/title |
| updated_date | source · DataCite | connector:datacite@1.0.0 |